Osmotic Pressure Equation:
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Osmotic pressure is the minimum pressure which needs to be applied to a solution to prevent the inward flow of its pure solvent across a semipermeable membrane. It's a colligative property, meaning it depends on the molar concentration of the solute but not its identity.
The calculator uses the osmotic pressure equation:
Where:
Explanation: The equation accounts for the number of particles the solute dissociates into (i), the concentration of the solution, and the temperature.
Details: Osmotic pressure is crucial in biological systems (like kidney function), industrial processes (reverse osmosis), and pharmaceutical applications (IV solutions).
Tips: Enter the Van't Hoff factor (1 for non-electrolytes, 2 for NaCl, etc.), molar concentration in mol/m³, and temperature in Kelvin. All values must be positive.
Q1: What is the Van't Hoff factor?
A: It represents the number of particles a compound dissociates into in solution (e.g., 1 for glucose, 2 for NaCl, 3 for CaCl₂).
Q2: Why is temperature in Kelvin?
A: The gas constant R uses Kelvin in its units, and absolute temperature is required for thermodynamic calculations.
Q3: What are typical osmotic pressure values?
A: Physiological saline (0.9% NaCl) has about 7.6 atm (770 kPa), while seawater is about 27 atm (2.7 MPa).
Q4: How does this relate to reverse osmosis?
A: Reverse osmosis requires pressure greater than the osmotic pressure to force solvent through the membrane against the concentration gradient.
Q5: What are limitations of this calculation?
A: It assumes ideal behavior and doesn't account for ion pairing or other non-ideal effects in concentrated solutions.