Rate Constant Equation:
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The rate constant (k) is a proportionality constant in the rate law that relates the reaction rate to the concentrations of reactants. It is specific to a particular reaction at a given temperature.
The calculator uses the rate law equation:
Where:
Explanation: The equation shows that the rate constant can be determined from experimental measurements of reaction rate and reactant concentrations.
Details: The rate constant is fundamental in chemical kinetics as it provides quantitative information about reaction speed and mechanism. It varies with temperature (following the Arrhenius equation) but is independent of reactant concentrations.
Tips: Enter reaction rate in M/s, reactant concentration in molarity (M), and the sum of reaction orders (must be ≥0). All values must be positive numbers.
Q1: What are typical units for rate constant?
A: Units vary with reaction order: 1st order (s⁻¹), 2nd order (M⁻¹s⁻¹), etc. The calculator will show appropriate units based on input.
Q2: How does temperature affect rate constant?
A: Rate constant increases with temperature according to the Arrhenius equation: k = Ae^(-Ea/RT).
Q3: What's the difference between rate and rate constant?
A: Rate measures how concentration changes with time, while rate constant is the proportionality factor in the rate law.
Q4: Can this be used for elementary reactions?
A: Yes, for elementary reactions the orders equal the stoichiometric coefficients. For complex reactions, orders must be determined experimentally.
Q5: How accurate is this calculation?
A: Accuracy depends on the precision of your experimental rate and concentration measurements.