Arrhenius Equation:
From: | To: |
Activation energy (Ea) is the minimum energy required for a chemical reaction to occur. It represents the energy barrier that must be overcome for reactants to transform into products.
The Arrhenius equation relates reaction rate constants to temperature:
Where:
Graph Method: Plot ln k vs 1/T (inverse temperature). The slope of the resulting line equals -Ea/R.
Details: Activation energy helps predict reaction rates at different temperatures and provides insight into reaction mechanisms. Lower Ea means faster reaction at given temperature.
Steps:
Q1: What units should the slope be in?
A: The slope should be in Kelvin (K) units from your ln k vs 1/T plot.
Q2: How many data points are needed?
A: At least 3-5 temperature points are recommended for accurate slope determination.
Q3: What if my graph isn't linear?
A: Non-linearity may indicate experimental error or that the reaction doesn't follow simple Arrhenius behavior.
Q4: Can I use different temperature units?
A: No, temperature must be in Kelvin for the Arrhenius plot.
Q5: What's the typical range for Ea values?
A: Most reactions have Ea between 50-250 kJ/mol, though some can be outside this range.