Boiling Point Elevation Equation:
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Boiling point elevation is the phenomenon where the boiling point of a liquid (typically water) increases when another compound is added, such that the solution has a higher boiling point than the pure solvent. This occurs whenever a non-volatile solute is added to a pure solvent.
The calculator uses the boiling point elevation equation:
Where:
Explanation: The equation shows that boiling point elevation is directly proportional to the molal concentration of the solute particles in the solution.
Details: Understanding boiling point elevation is crucial in various applications including cooking, antifreeze formulations, and industrial processes where precise temperature control is needed.
Tips: Enter molality in mol/kg and Van't Hoff factor (typically 1 for non-electrolytes, higher for electrolytes). All values must be valid (molality > 0, i ≥ 1).
Q1: Why is Kb different for different solvents?
A: The ebullioscopic constant (Kb) depends on the properties of the solvent. Water has Kb = 0.512 °C·kg/mol, while other solvents have different values.
Q2: What is the Van't Hoff factor?
A: The Van't Hoff factor (i) represents the number of particles the solute dissociates into. For NaCl, i ≈ 2; for CaCl2, i ≈ 3.
Q3: Does boiling point elevation depend on the identity of the solute?
A: Only indirectly through the Van't Hoff factor. The primary determinants are the concentration of particles and the solvent's properties.
Q4: How accurate is this calculation?
A: It's accurate for dilute solutions. For concentrated solutions, deviations from ideal behavior become significant.
Q5: Can this be used for solvents other than water?
A: No, this calculator is specific to water. Other solvents have different Kb values.